HW06 - Buffers, Titrations, and Polyprotics

Question 1 1 pts

When an acid and base neutralize each other, the products are generally water and...

  1. an ion.
  2. a gel.
  3. a colloid.
  4. a salt.
Question 2 1 pts

How many moles of Ca(OH)2 are needed to neutralize three moles of HCl?

  1. 1
  2. 1.5
  3. 3
  4. 2
Question 3 1 pts

An aqueous solution is prepared with 2 moles of HCl and 1 mole of Ca(OH)2. The resulting solution contains mainly...

  1. water, Cl- ions, OH- ions, and Ca2+ ions.
  2. water, Cl- ions, H+ ions, and Ca2+ ions.
  3. water, Cl- ions, and Ca2+ ions.
  4. water, Cl- ions, H+ ions, OH- ions, and Ca2+ ions.
Question 4 1 pts

Identify the products of the following chemical reaction:

3LiOH + H3PO4

  1. Li3PO4 + 3H2O
  2. Li3P + 2H2O + H3O5
  3. 3H+ + 3O2 + H3Li3
  4. 3LiH + (OH)3PO4
Question 5 1 pts

Identify the products of the following chemical reaction:

Sr(OH)2 + 2HNO3

  1. Sr(NO2)2 + 2H2O2
  2. SrNO3 + H2O
  3. SrH2 + HNO5
  4. Sr(NO3)2 + 2H2O
Question 6 1 pts

Aqueous ammonia can be used to neutralize sulfuric acid and nitric acid to produce two salts extensively used as fertilizers. They are...

  1. NH4SO4 and NH4NO3, respectively
  2. (NH4)2SO4 and NH4NO3, respectively
  3. NH4SO3 and NH4OH, respetively
  4. cyanamide and cellulose nitrate, respectively
Question 7 1 pts

Identify the salt that is produced from the acid-base neutralization reaction between potassium hydroxide and acetic acid.

  1. potassium amide
  2. potassium cyanide
  3. potassium acetate
  4. potassium formate
Question 8 1 pts

What is the pH of an aqueous solution that is 0.018 M C6H5NH2 (Kb = 4.3 × 10-10) and 0.12 M C6H5NH3Cl?

  1. 2.87
  2. 4.02
  3. 3.81
  4. 4.63
Question 9 1 pts

A buffer solution is made by dissolving 0.45 moles of a weak acid (HA) and 0.33 moles of KOH into 710 mL of solution. What is the pH of this buffer? Ka = 6 × 10-6 for HA.

  1. 13.23
  2. 5.22
  3. 5.66
  4. 8.34
Question 10 1 pts

Which one of the following combinations is NOT a buffer solution?

  1. NH3 and (NH4)2SO4
  2. CH3COOH and NaCH3COO
  3. HCN and NaCN
  4. HBr and KBr
Question 11 1 pts

Which of the following mixtures will be a buffer when dissolved in a liter of water?

  1. 0.2 mol HBr and 0.1 mol NaOH
  2. 0.3 mol NaCl and 0.3 mol HCl
  3. 0.2 mol HF and 0.1 mol NaOH
  4. 0.1 mol Ca(OH)2 and 0.3 mol HI
Question 12 1 pts

What is the pH of a solution which is 0.600 M in dimethylamine ((CH3)2NH) and 0.400 M in dimethylamine hydrochloride ((CH3)2NH2Cl)? Kb for dimethylamine = 7.4 × 10-4

  1. 11.05
  2. 10.87
  3. 10.78
  4. 11.21
Question 13 1 pts

What would be the final pH if 0.0100 moles of solid NaOH were added to 100mL of a buffer solution containing 0.600 molar formic acid (ionization constant = 1.8 × 10-4) and 0.300 M sodium formate?

  1. 3.65
  2. 3.44
  3. 3.84
  4. 4.05
Question 14 1 pts

A buffer was prepared by mixing 0.200 moles of ammonia (Kb = 1.8 × 10-5) and 0.200 moles of ammonium chloride to form an aqueous solution with a total volume of 500 mL. 250 mL of the buffer was added to 50.0 mL of 1.00 M HCl. What is the pH of this second solution?

  1. 8.38
  2. 8.53
  3. 8.78
  4. 8.18
Question 15 1 pts

A solution is 0.30 M in NH3. What concentration of NH4Cl would be required to achieve a buffer solution with a final pH of 9.0? Kb = 1.8 × 10-5 for NH3.

  1. 0.54 M
  2. 0.32 M
  3. 0.45 M
  4. 0.10 M
Question 16 1 pts

What is the pH at the half-stoichiometric point for the titration of 0.22 M HNO2(aq) with 0.1 M KOH(aq)? For HNO2, Ka = 4.3 × 10-4.

  1. 2.01
  2. 7.00
  3. 2.31
  4. 3.37
Question 17 1 pts

For the titration of 50.0 mL of 0.020 M aqueous salicylic acid with 0.020 M KOH (aq), calculate the pH after the addition of 55.0 mL of the base. For salicylic acid, pKa = 2.97.

  1. 10.98
  2. 11.26
  3. 7.00
  4. 11.02
Question 18 1 pts

Consider the titration of 50.0 mL of 0.0200 M HClO(aq) with 0.100 M NaOH(aq). What is the formula of the main species in the solution after the addition of 10.0 mL of base?

  1. HClO
  2. NaOH
  3. ClO2
  4. ClO-
Question 19 1 pts

50.0 mL of 0.0018 M aniline (a weak base) is titrated with 0.0048 M HNO3. How many mL of the acid are required to reach the equivalence point?

  1. 4.21 mL
  2. 18.8 mL
  3. This is a bad titration as HNO3 is not a strong acid.
  4. 133 mL
Question 20 1 pts

When we titrate a weak base with a strong acid, the pH at the equivalence point will be...

  1. It is impossible to know unless we are given the Kb of the weak base.
  2. pH > 7
  3. pH = 0
  4. pH < 7
Question 21 1 pts

What is the pH at the equivalence point in the titration of 10.0 mL of 0.35 M unknown acid HZ with 0.200 M NaOH? Ka = 2.4 × 10-7 for the unknown acid HZ

  1. 7.00
  2. 9.86
  3. 10.1
  4. 4.14
Question 22 1 pts

What is the pH at the equivalence point of the titration pictures below?

  1. 8
  2. 5
  3. 9
  4. 2
Question 23 1 pts

Look at the titration diagram in the question above. What type of titration is occurring?

  1. a weak base titrated with a strong acid
  2. a strong base titrated with a weak acid
  3. a strong base titrated with a strong acid
  4. a weak base titrated with a weak acid
Question 24 1 pts

The acid form of an indicator is yellow and its anion is blue. The Ka of this indicator is 10-5. What will be the approximate pH range over which this indicator changes color?

  1. 6 < pH < 8
  2. 4 < pH < 6
  3. 5 < pH < 7
  4. 3 < pH < 5
Question 25 1 pts

The unionized form of an acid indicator is yellow and its anion is blue. The Ka of this indicator is 10-5. What will be the color of the indicator in a solution of pH 3?

  1. orange
  2. blue
  3. green
  4. yellow
Question 26 2 pts

Aspartic acid is a polypeptide side chain found in proteins. The pKa of aspartic acid is 3.86. If this polypeptide were in an aqueous solution with a pH of 7, the side chain would have what charge?

  1. positive
  2. negative
  3. neutral
  4. there is no way to know
Question 27 1 pts

Blood contains a buffer of carbonic acid (H2CO3) and hydrogen carbonate ion (HCO3) that keeps the pH at a relatively stable 7.40. What is the ratio of [HCO3] / [H2CO3] in blood? Ka1 = 4.30 × 10-7 for H2CO3 (Hint: Assume [CO32–] = 0)

  1. 10.8
  2. 3.98 x 10-8
  3. 0.0926
  4. 1.71 x 10-14
Question 28 2 pts

H2SO4 is a strong acid because the first proton ionizes 100%. The Ka of the second proton is 1.1 × 10-2. What would be the pH of a solution that is 0.100 M H2SO4? Account for the ionization of both protons.

  1. 0.955
  2. 0.963
  3. 2.05
  4. 1.00