VSEPR Theory
... brought to you by Dr. McCord
the FIVE core electronic geometries
These are the 5 core geometries that all VSEPR theory is based on. There are another 6 geometries that are subsets of these five. The subsets are made by substituting electron lone pairs into the positions instead of atoms.
Click on any of the geometry names to open a page about that geometry and all its subsets.
formula: AX2
hybridization: sp
angle: 180°
examples: BeCl2, CO2, C2H2
formula: AX3
hybridization: sp2
angle: 120°
examples: BH3, H2CO, NO3–, C2H4
formula: AX4
hybridization: sp3
angle: 109.5°
examples: CH4, SO42–, C2H6
formula: AX5
hybridization: sp3d
angles: 180°, 120°, 90°
examples: PF5, AsCl5
formula: AX6
hybridization: sp3d2
angles: 180°, 90°
examples: SF6, SeCl6